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DID YOU KNOW

Did you know that according to experts, music trends in 2018 includes hip-hop, music streaming, and live concerts? To back this up, Drake, an artist rooted in hip-hop, came out as the most popular musician in the United States in 2017. Music as part of our daily lives is deeply rooted in the cultural diaspora we are and in 2016, the music industry has redeemed itself from its lumbering growth in the previous years. According to an article published on Rolling Stone, the industry has hit revenue of 7.7 billion US dollars in 2016—the highest gross since 2009. The drastic growth can be attributed to the growing popularity of various paid streaming platforms, live events, social media channels, and the easy access to music production tools, especially software have replaced the major music distribution channels of yesteryear. This is despite the rise of other sources, specifically music torrenting sites. 2018 music technology puts Spotify on the top trend with its remarkable growth over the past few years amidst the 1.6 billion copyright lawsuit it's facing while SoundCloud remains to struggle to maintain its place in the industry despite laying off 40% of its workforce and shutting down offices in London and San Francisco. While streaming is slowly reaching its prosperity, sales of compact disc continue to slow down with only 99.4 million physical albums sold in 2016—the lowest number since 1986. Nevertheless, the music revenue worldwide is projected to reach 57 billion US dollars by 2021, according to Statista.

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    TorrentProject is a torrent search engine which offers a collection of more than 10 million torrents of movies, games, music, ebooks, and software which can be downloaded with zero restrictions. *NO LONGER AVAILABLE*
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NIOSH Manual of Analytical Methods (1994)
National Institute for Occupational Safety and Health
Copper (Dust and Fume) (7029)

COPPER (dust and fume)

Cu

MW: 63.54

CAS: 7440-50-8 (Cu)

METHOD: 7029, Issue 2

7029

RTECS: GL5325000

EVALUATION: FULL

OSHA : 0.1 mg/m 3 (fume); 1 mg/m 3 (dust)NIOSH: 0.1 mg/m 3 (fume); 1 mg/m 3 (dust)ACGIH: 0.2 mg/m 3 (fume);1 mg/m 3 (dust, mist)

Issue 1: 15 February 1984Issue 2: 15 August 1994

PROPERTIES: soft metal; valence +1, +2 in saltsMP 1083 °C

SYNONYMS: vary depending upon the compound; CAS #1317-39-1 (Cu 2O), CAS #1317-38-0 (CuO)

SAMPLINGSAMPLER:

FILTER(0.8-µm cellulose ester membrane)

MEASUREMENTTECHNIQUE:

ATOMIC ABSORPTION, FLAME

ANALYTE:

copper

ASHING:

conc. HNO 3, 6 mL, 140 °C;conc. HCl, 6 mL, 400 °C

FLOW RATE: 1 to 3 L/minVOL-MIN:-MAX:

50 L @ 0.1 mg/m 31500 L

SHIPMENT:

routine

0.5 N HCl; 25 mL

FINAL SOLUTION:

SAMPLESTABILITY:BLANKS:

FLAME:

air-acetylene, oxidizing

stable

WAVELENGTH:

324.7 nm

2 to 10 field blanks per set

BACKGROUND CORRECTION: not required

ACCURACY

CALIBRATION:

standard solutions ofCu 2+ in 0.5 N HCl

RANGE:

5 to 125 µg per sample [4]

RANGE STUDIED: 0.05 to 0.59 mg/m 3 (fume) [1,2]0.47 to 1.8 mg/m 3 (dust) [3]

ESTIMATED LOD: 0.05 µg per sample [5]

BIAS:

- 0.44%

PRECISION (Sr):

ˆ ):OVERALL PRECISION (SrT

0.044 (fume) [1,2]0.051 (dust)[3]± 11.0%

ACCURACY:

0.03 [1,3,5]

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APPLICABILITY: The working range is 0.05 to 1.3 mg/m 3 for a 100-L air sample. This is an elemental analysis, applicable toeither dust or fume, with an additional separation step to quantitate soluble copper dust (e.g., CuSO 4) in the presence of copperfume. Aliquots of the samples can be analyzed separately for many additional metals.

INTERFERENCES: Background correction is not required. Interferences to the fume/soluble dust separation step includeinsoluble copper compounds and copper compounds such as copper acetate which form insoluble hydroxides when dissolved inwater.

OTHER METHODS: This method combines and replaces P&CAM 173 [5], S354 [4], and S186 [6]. Method 7300, plasmaemission (ICP-AES), is an alternate analytical method.

NIOSH Manual of Analytical Methods (NMAM), Fourth Edition, 8/15/94 COPPER (dust and fume): METHOD 7029, Issue 2, dated 15 August 1994 - Page 2 of 4EQUIPMENT:

REAGENTS:1.2.3.4.

5.6.7.

Nitric acid, conc.Hydrochloric acid, conc.Hydrochloric acid, 0.5 N. Add 41.5 mL conc.HCl to water, dilute to 1 L.Calibration stock solution, 1000 µg/mL.Commercially available, or dissolve 1.000 gCu metal in minimum volume of (1:1) HNO 3.Dilute to 1 L with 0.5 N HCl.Distilled-deionized water.Air, filtered.Acetylene.

See SPECIAL PRECAUTIONS.

1. Sampler: cellulose ester membrane filter,0.8-µm pore size, 37 mm-diameter; in cassettefilter holder.2. Personal sampling pump, 1 to 3 L/min, withflexible connecting tubing.3. Atomic absorption spectrophotometer with anair-acetylene burner head and copper hollowcathode lamp and two-stage regulators for airand acetylene.4. Beakers, Phillips, 125-mL, or Griffin, 50-mL,with watchglass covers.*5. Volumetric flasks, 25-mL.*6. Assorted volumetric pipets, as needed.*7. Hotplate, surface temperature 140 °C and400 °C.8. Equipment for fume/dust separation step:a. cellulose ester membrane filters, 47-mm,0.3-µm pore size (Millipore PHWP orequivalent);b. cellulose ester membrane filter, 47-mm,5-µm pore size (Millipore SMWP orequivalent);c. filtration apparatus (Gelman No. 1107 orequivalent).

Clean all glassware with conc. nitric acidand rinse thoroughly with distilled ordeionized water before use.

SPECIAL PRECAUTIONS: Perform all acid digestions in a fume hood.

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SAMPLING:1.2.

Calibrate each personal sampling pump with a representative sampler in line.Sample at an accurately known flow rate between 1 and 3 L/min for a sample size of 50 to1500 L. Do not exceed a total filter loading of ca. 2 mg total dust.

SAMPLE PREPARATION:

3.

NOTE: The following sample preparation gave quantitative recovery (see EVALUATION OFMETHOD). Other quantitative ashing techniques (e.g., HNO 3-HClO 4 [Method 7300])may be useful alternatives, especially if several metals are to be determined on a singlefilter.Proceed to step 4 if fume/dust separation is not desired. For fume/dust separation:a. Using forceps, prewet a 47-mm, 0.3-µm pore size cellulose ester membrane filter by placingit on the surface of distilled water. Remove the filter, tap off excess water, and mount it onthe filtration unit.b. Transfer the sample filter from the cassette filter holder to the filtration unit, placing itconcentrically on top of the 47-mm filter with the fume deposit up.NIOSH Manual of Analytical Methods (NMAM), Fourth Edition, 8/15/94 COPPER (dust and fume): METHOD 7029, Issue 2, dated 15 August 1994 - Page 3 of 4c.

4.5.

6.

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7.8.

Apply and release the vacuum so that the 37-mm filter is gently wetted from the moistureretained on the 47-mm filter. This also insures the removal of any air bubbles between thefilters.d. When the fume sample is visually clear of air bubbles and wet throughout, apply a vacuumof 10 to 15 PSIG (69 to 103 kPa). Release the vacuum.e. Place a 47-mm, 5-µm cellulose ester membrane filter on the surface of water to wet it,remove excess water by blotting with tissue, and place it concentrically on top of the 37-mmfilter. Press the surface of the top filter with a clean tissue to insure that no air bubblesremain between any of the filters.f. Mount the upper part of the filtration unit, add 5 mL of distilled water, and allow vacuum todraw water through the filters. Repeat with 5 mL more water. Combine the filtrates whichcontain soluble copper compounds in a clean beaker. Start reagent blanks at this point.g. Transfer all filters to a clean beaker. Proceed to step 5.NOTE: Each sample blank is a combination of three filters.Open the cassette filter holders and transfer the samples and blanks to clean beakers.Add 6 mL conc. HNO 3. Cover with a watchglass and heat on hotplate (140 °C) until the volumeis reduced to approximately 0.5 mL. Repeat two more times using 2 mL conc. HNO 3 each time.NOTE: Start reagent blanks at this point if step 3 was omitted.Add 2 mL conc. HCl, cover with a watchglass, heat on hotplate (400 °C) until the volume isreduced to approximately 0.5 mL. Repeat two more times using 2 mL conc. HCl. Do not allowthe solution to go to dryness at any point.Cool solution and add 10 mL distilled water.Transfer the solution quantitatively to a 25-mL volumetric flask. Dilute to volume with distilledwater.

CALIBRATION AND QUALITY CONTROL:9.

10.11.12.13.14.

Calibrate daily with at least six working standards. Add known amounts, covering the range 0 to125 µg Cu per sample, of calibration stock solution to 25-mL volumetric flasks and dilute tovolume with 0.5 N HCl.Analyze the working standards together with the blanks and samples (steps 15 and 16).Prepare a calibration graph by plotting absorbance versus solution concentration (µg/mL).Aspirate a standard for every 10 samples to check instrument drift.Check analytical recoveries with at least one spiked media blank per 10 samples.Use method of additions occasionally to check for interferences.

MEASUREMENT:15.16.

Set spectrophotometer as specified by the manufacturer and to conditions on page 7029-1.Aspirate standards, samples, and blanks. Record absorbance readings.NOTE: If the absorbance values for the samples are above the linear range of the standards,dilute the sample solutions with 0.5 N HCl, reanalyze, and apply the appropriate dilutionfactor in the calculations.

CALCULATIONS:17.18.

Using the measured absorbances, calculate the corresponding concentrations (µg/mL) of copperin the sample, C s, and average media blank, C b, from the calibration graph.Using the solution volumes (mL) of the sample, V s, and media blanks, V b, calculate theconcentration of copper in the air volume sampled, V (L):

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NIOSH Manual of Analytical Methods (NMAM), Fourth Edition, 8/15/94 COPPER (dust and fume): METHOD 7029, Issue 2, dated 15 August 1994 - Page 4 of 4

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EVALUATION OF METHOD:Method S186 was validated on August 29, 1975, with overall sampling and analytical precision,SˆrT =30.051, over the range 0.47 to 1.8 mg/m for a 90-L sample of CuO dust [3,6] and Method S354 wasvalidated on September 30, 1977, with overall sampling and analytical precision, SˆrT = 0.058, over therange 0.05 to 0.37 mg/m 3 for a 480-L sample of Cu fume [1,4]. Copper fume atmospheres weregenerated by thermal decomposition and subsequent oxidation of cupric acetate aerosol. The size ofthe copper fume was 0.04 to 0.14 µm by electron microscopy and the collection efficiency of thesampler for this fume was 1.00 [1,4,9].The dust-fume separation step was evaluated with samples laden with copper fume generated fromcopper welding; the samples were then placed into a dust generation system and overlaid with a knowndeposition of copper sulfate dust. With a dust loading of about 600 µg CuSO 4 and fume concentrationsof 0.13 to 0.59 mg/m 3, an average of 96.5% of the dust was removed. The analysis of the copper fumehad a pooled Sr of 4.4% with an average bias of 5.3% [2].Efficiencies of removal of Cu dust and fume were determined from samples containing only dust or onlyfume. Measured efficiencies were: (1) from filters containing 213 to 265 µg CuSO 4, an average of97.8% was removed using 10 to 50 mL water; (2) filters laden with ca. 200 µg Cu/filter lost 11.5% Cuafter washing with 10 mL H 2O. Because the non-equilibrium nature of the washing process does notlend itself to accurate prediction of the amount of copper fume removed by the wash water, nocorrection factor for the amount of fume removed was determined or employed. The elemental analysisused in the evaluation did not distinguish between copper from the fume and from the dust [2].

REFERENCES:[1] Backup Data Report for Copper Fume, S354, prepared under NIOSH Contract No. 210-76-0123,available as 'Ten NIOSH Analytical Methods, Set 5,' Order No. PB 287-499 from NTIS, Springfield,VA 22101.[2] Carsey, T. Development of a Sampling and Analytical Method for Copper Fume, final report,NIOSH (DPSE) (unpublished, September, 1982).[3] Documentation of the NIOSH Validation Tests, U.S. Department of Health, Education, and Welfare,Publ. (NIOSH) 77-185 (1977).[4] Ibid, V. 4, Method S354, U.S. Department of Health, Education, and Welfare, Publ. (NIOSH) 78-175(1978).[5] NIOSH Manual of Analytical Methods, 2nd ed., V. 5, P&CAM 173, U.S. Department of Health,Education, and Welfare, Publ. (NIOSH) 79-141 (1979).[6] Ibid, V. 3, Method S186, U.S. Department of Health, Education, and Welfare, Publ. (NIOSH)77-157-C (1977).[7] Winefordner, J. D., Ed. Spectrochemical Methods of Analysis , John Wiley & Sons (1971).[8] Analytical Methods for Atomic Absorption Spectrophotometry, Perkin-Elmer (1976).[9] NIOSH Research Report-Development and Validation of Methods for Sampling and Analysis ofWorkplace Toxic Substances, U.S. Department of Health and Human Services, Publ. (NIOSH)80-133 (1980).

METHOD REVISED BY:Mark Millson, NIOSH/DPSE, and R. DeLon Hull, Ph.D., NIOSH/DBBS; originally validated under NIOSHContracts CDC-94-74-45 and 210-76-0123.NIOSH Manual of Analytical Methods (NMAM), Fourth Edition, 8/15/94

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